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===<!--7.1.2 -->Electroless Plating===
Electroless plating is defined as a coating process which is performed without the use of an external current source. It allows a uniform metal coating independent of the geometrical shape of the parts to be coated. Because of the very good dispersion capability of the used electrolytes also cavities and the inside of drilled holes in parts can be coated for example. In principal two different mechanisms are employed for electroless plating: processes in which the carrier material serves as a reduction agent (Immersion processes) and those in which a reduction agent is added to the electrolyte (Electroless processes).
====<!--7.1.2.2 -->Immersion Processes====The immersion processes are usually applied in the plating of the metals gold, silver, and tin. If the material to be coated is less precious, i.e. exhibits a negative standard potential against the metal ions in the surrounding solution, it goes into solution releasing electrons while the more precious metal ions are reduced by absorbing electrons and being deposited on the electrode. This process can continue until the complete surface of the substrate is covered with a thin layer of the more precious metal. This limits the maximum achievable layer thickness to approx. 0.1 μm <xr id="tab:Immersion_Gold_Electrolytes"/> <!--(Table 7.5)-->.
<figtable id="tab:Immersion_Gold_Electrolytes">
<caption>'''<!--Table 7.5: -->Immersion Gold Electrolytes'''</caption>
{| class="twocolortable" style="text-align: left; font-size: 12px"
</figtable>
====<!--7.1.2.3 -->Electroless Processes====
The electroless metal plating with adding reduction agents to the electrolyte is based on the oxidation of the reducing agent with release of electrons which then in turn reduce the metal ions. To achieve a controlled deposition from such solutions the metal deposition has to happen through the catalytic influence of the substrate surface.
Otherwise a “wild” "wild" uncontrollable deposition would occur. In most cases palladium containing solutions are used for the activation which seed the
surfaces with palladium and act as catalysts in the copper and nickel electrolytes.
deposits.
====<!--7.1.2.4 -->Electroless Deposition of Nickel/Gold====
Electroless deposited nickel coatings with an additional immersion layer of gold are seeing increased importance in the coating of printed circuit boards (PCBs). The process sequence is shown in <xr id="fig:Electroless Deposition of Nickel Gold"/> <!--(Fig. 7.2) --> using the example of the DODUCHEM process.
<figure id="fig:Electroless Deposition of Nickel Gold">
[[File:Electroless Deposition of Nickel Gold.jpg|right|thumb|Electroless Deposition of Nickel/Gold]]
(DODUBOND process). This Pd layer acts as a diffusion barrier and allows the usage of this surface combination also for gold wire bonding.
As an alternative, for gold wire bonding applications a thicker gold layer of 0.2 – 0.5 μm can be applied using an electroless process. Typical electrolytes work at a temperature of approx. 80°C with deposition rates of 0.3 – 0.4 μm per 30 minutes. There are however limitations with these electroless electrolytes concerning their stability and the robustness of the process compared to other electroplating processes which reduces their wider usage <xr id="fig:Coating composition of a printed circuit board"/> <!--(Fig. 7.3)-->.
<figure id="fig:Coating composition of a printed circuit board">
</figure>
====<!--7.1.2.5 -->Immersion Deposition of Tin====A tin coating by ion exchange is usually not possible since copper is the more precious metal. By adding thio-urea the electro-chemical potential of copper is reduced to a level (approx. 450 mV, significantly lower than tin) that allows the exchange reaction. Using a suitable electrolyte composition and enhancer solutions like with the DODUSTAN process <xr id="fig:Process flow for electroless tin deposition using the DODUSTAN process"/> <!--(Fig. 7.4) --> tin coatings can be produced that, even under usually unfavorable conditions of copper concentrations of 7 g/l in the electrolyte, are well solderable.
<figure id="fig:Process flow for electroless tin deposition using the DODUSTAN process">
