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Surface Coating Technologies

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passivation coatings are applied as protection against silver sulfide formation.
===7.1 Coatings from the Liquid Phase===
For thin coatings starting from the liquid phase two processes are used
differentiated by the metallic deposition being performed either with or without
while the second one is a chemical deposition process.
===7.1.1 Electroplating (or Galvanic Deposition)===
For electroplating of metals, especially precious metals, water based solutions
(electrolytes) are used which contain the metals to be deposited as ions (i.e.
well as the most widely used electroplating processes are described.
===7.1.1.1 = Electroplating Solutions – Electrolytes====
The actual metal deposition occurs in the electrolytic solution which contains
the plating material as metal ions. Besides this basic ingredient, the electrolytes
deposit.
===7.1.1.1.1 == Precious Metal Electrolytes=====
All precious metals can be electroplated with silver and gold by far the most
widely used ones ''(Tables 7.1 and 7.2)''.
<table border="1" cellspacing="0" style="border-collapse:collapse"><tr><td><p class="s8">AUROMET TN</p></td><td><p class="s8">3.2 - 4.2</p></td><td><p class="s8">ca. 70</p></td><td><p class="s8">99.99% Au</p></td><td><p class="s8">Base-deposits</p></td></tr><tr><td><p class="s8">AUROMET XPH</p></td><td><p class="s8">0.3 - 0.6</p></td><td><p class="s8">160 - 180</p></td><td><p class="s8">99.8% Au</p></td><td><p class="s8">Base-deposits for stainless steel etc.</p></td></tr><tr><td><p class="s8">DODUREX COC</p></td><td><p class="s8">4.6 - 4.9</p></td><td><p class="s8">160 - 180</p></td><td><p class="s8">99.6% Au</p></td><td><p class="s8">Printed circuit boards, connectors, contact parts, etc.; hard gold coatings for rack and barrel plating</p></td></tr><tr><td><p class="s8">DODUREX HS 100</p></td><td><p class="s8">4.3 - 4.6</p></td><td><p class="s8">160 - 180</p></td><td><p class="s8">99.6% Au</p></td><td><p class="s8">High speed process for connectors and</p><p class="s8">PCB plating</p></td></tr><tr><td><p class="s8">PURAMET 202</p><p class="s8">PURAMET 402</p></td><td><p class="s8">5.5 - 6.5</p><p class="s8">7.0 - 7.5</p></td><td><p class="s8">60 - 80</p><p class="s8">60 - 80</p></td><td><p class="s8">99.99% Au</p><p class="s8">99.99% Au</p></td><td><p class="s8">High purity gold coatings for electrical</p><p class="s8">and electronic parts incl. semi conductors and PCBs; for demanding requirement on bonding properties</p></td></tr></table>
===7.1.1.1.2 == Non-Precious Metal Electrolytes=====
The most important non-precious metals that are deposited by electroplating
are: Copper, nickel, tin, and zinc and their alloys. The deposition is performed in
Table 7.2: Typical Electrolytes for the Deposition of Non-Precious Metals
===7.1.1.2 = Electroplating of Parts====
The complete or all-around electroplating of small mass produced parts like
contact springs, rivets, or pins is usually done as mass plating in electroplating
standards, and customer specifications resp.
===7.1.1.3 = Electroplating of Semi-finished Materials====
The process for overall electroplating of strips, profiles, and wires is mostly
performed on continuously operating reel-to-reel equipment. The processing
cracks are generated in the electroplated layers.
===7.1.1.4 = Selective Electroplating====
Since precious metals are rather expensive it is necessary to perform the
electroplating most economically and coat only those areas that need the layers